| MD | Players | Nationality | DOB | A(D) |
|---|---|---|---|---|
| 22-Oct-2008 | Ignacio Camacho | Spain | 04-May-1990 | 18(172) |
| 03-Nov-2021 | Javier Serrano | Spain | 16-Jan-2003 | 18(292) |
| 01-Oct-2013 | Oliver Torres | Spain | 10-Nov-1994 | 18(326) |
| 01-Nov-2022 | Pablo Barrios | Spain | 15-Jun-2003 | 19(139) |
| 11-Sep-1996 | Leonardo Biagini | Argentina | 13-Apr-1977 | 19(151) |
| 22-Oct-2008 | Alvaro Dominguez | Spain | 16-May-1989 | 19(159) |
| 05-Mar-1997 | Veljko Paunovic | Serbia and Montenegro | 21-Aug-1977 | 19(196) |
| 11-Dec-2013 | Javi Manquillo | Spain | 05-May-1994 | 19(220) |
| 25-Nov-2020 | Sergio Camello | Spain | 10-Feb-2001 | 19(288) |
| 16-Sep-2014 | Saul Niguez | Spain | 21-Nov-1994 | 19(299) |
| 26-Nov-2014 | Jose Maria Gimenez | Uruguay | 20-Jan-1995 | 19(310) |
| 18-Sep-2019 | Joao Felix | Portugal | 10-Nov-1999 | 19(312) |
| 11-Dec-2018 | Francisco Montero | Spain | 14-Jan-1999 | 19(331) |
| 15-Mar-2016 | Lucas Hernandez | France | 14-Feb-1996 | 20(30) |
| 16-Sep-2008 | Ever Banega | Argentina | 29-Jun-1988 | 20(79) |
| 15-Sep-2009 | Sergio Asenjo | Spain | 28-Jun-1989 | 20(79) |
| 16-Sep-2008 | Sergio Aguero | Argentina | 02-Jun-1988 | 20(106) |
| 30-Sep-2015 | Angel Correa | Argentina | 09-Mar-1995 | 20(205) |
| 04-Oct-2023 | Ilias Kostis | Cyprus | 27-Feb-2003 | 20(219) |
| 18-Sep-2013 | Leo Baptistao | Brazil | 26-Aug-1992 | 21(23) |
| 18-Sep-2013 | Thibaut Courtois | Belgium | 11-May-1992 | 21(130) |
| 18-Sep-2019 | Renan Lodi | Brazil | 08-Apr-1998 | 21(163) |
| 16-Sep-2014 | Jan Oblak | Slovenia | 07-Jan-1993 | 21(252) |
| 18-Sep-2013 | Jorge Koke | Spain | 08-Jan-1992 | 21(254) |
| 15-Sep-2015 | Luciano Vietto | Argentina | 05-Dec-1993 | 21(284) |
| 21-Oct-2015 | Yannick Carrasco | Belgium | 04-Sep-1993 | 22(47) |
| 16-Sep-2008 | Raul Garcia | Spain | 11-Jul-1986 | 22(68) |
| 18-Sep-2018 | Rodri Hernandez | Spain | 22-Jun-1996 | 22(88) |
| 01-Oct-2008 | Miguel de las Cuevas | Spain | 19-Jun-1986 | 22(105) |
| 03-Nov-2021 | Matheus Cunha | Brazil | 27-May-1999 | 22(161) |
| 11-Sep-1996 | Santi | Spain | 09-Mar-1974 | 22(187) |
| 05-Apr-2016 | Thomas Partey | Ghana | 13-Jun-1993 | 22(297) |
| 15-Mar-2016 | Matias Kranevitter | Argentina | 21-May-1993 | 22(299) |
| 18-Sep-2018 | Thomas Lemar | France | 12-Nov-1995 | 22(311) |
| 06-Nov-2013 | Josuha Guilavogui | France | 19-Sep-1990 | 23(48) |
| 15-Sep-2009 | Jose Manuel Jurado | Spain | 29-Jun-1986 | 23(78) |
| 11-Sep-1996 | Juan Carlos | Spain | 05-Apr-1973 | 23(159) |
| 19-Sep-2023 | Rodrigo Riquelme | Spain | 02-Apr-2000 | 23(169) |
| 06-Nov-2018 | Gelson Martins | Portugal | 11-May-1995 | 23(179) |
| 11-Sep-1996 | Juan Esnaider | Argentina | 05-Mar-1973 | 23(190) |
| 26-Nov-2014 | Raul Jimenez | Mexico | 05-May-1991 | 23(205) |
| 22-Oct-2014 | Antoine Griezmann | France | 21-Mar-1991 | 23(215) |
| 30-Sep-2009 | Roberto Gago | Spain | 10-Feb-1986 | 23(232) |
| 25-Sep-1996 | Roberto | Spain | 15-Jan-1973 | 23(253) |
| 19-Sep-2023 | Samuel Lino | Brazil | 23-Dec-1999 | 23(270) |
| 01-Oct-2008 | Florent Sinama-Pongolle | France | 20-Oct-1984 | 23(346) |
| 11-Sep-1996 | Radek Bejbl | Czech Republic | 29-Aug-1972 | 24(13) |
| 01-Oct-2019 | Mario Hermoso | Spain | 18-Jun-1995 | 24(105) |
| 11-Sep-1996 | Kiko | Spain | 26-Apr-1972 | 24(138) |
| 07-Sep-2022 | Nahuel Molina | Argentina | 06-Apr-1998 | 24(154) |
MD = Match date,
DOB = Date Of Birth,
A(D) = Age(Days).