| 8 | Wissam Ben Yedder | Group Stage | UEFA Champions League 17/18 |
| 6 | Youssef En-Nesyri | Group Stage | UEFA Champions League 20/21 |
| 5 | Frederic Kanoute | Group Stage | UEFA Champions League 07/08 |
| 4 | Luis Fabiano | Group Stage | UEFA Champions League 07/08 |
| 2 | Youssef En-Nesyri | Group Stage | UEFA Champions League 22/23 |
| 2 | Ivan Rakitic | Group Stage | UEFA Champions League 21/22 |
| 2 | Luuk De Jong | Group Stage | UEFA Champions League 20/21 |
| 2 | Ivan Rakitic | Group Stage | UEFA Champions League 20/21 |
| 2 | Wissam Ben Yedder | Group Stage | UEFA Champions League 16/17 |
| 2 | Ever Banega | Group Stage | UEFA Champions League 15/16 |
| 2 | Yevhen Konoplyanka | Group Stage | UEFA Champions League 15/16 |
| 2 | Sergio Ramos | Group Section | UEFA Champions League 23/24 |
| 2 | Nemanja Gudelj | Group Section | UEFA Champions League 23/24 |
| 2 | Youssef En-Nesyri | Group Section | UEFA Champions League 23/24 |
| 2 | Sebastien Squillaci | Group Stage | UEFA Champions League 09/10 |
| 2 | Frederic Kanoute | Group Stage | UEFA Champions League 09/10 |
| 2 | Jesus Navas | Group Stage | UEFA Champions League 09/10 |
| 2 | Luis Fabiano | Group Stage | UEFA Champions League 09/10 |
| 2 | Renato | Group Stage | UEFA Champions League 07/08 |
| 2 | Julien Escude | Group Stage | UEFA Champions League 07/08 |
| 2 | Seydou Keita | Group Stage | UEFA Champions League 07/08 |
| 2 | Dani Alves | Group Stage | UEFA Champions League 07/08 |
| 1 | Rafa Mir | Group Stage | UEFA Champions League 22/23 |
| 1 | Tanguy Nianzou | Group Stage | UEFA Champions League 22/23 |
| 1 | Isco | Group Stage | UEFA Champions League 22/23 |
| 1 | Gonzalo Montiel | Group Stage | UEFA Champions League 22/23 |
| 1 | Lucas Ocampos | Group Stage | UEFA Champions League 21/22 |
| 1 | Joan Jordan | Group Stage | UEFA Champions League 21/22 |
| 1 | Rafa Mir | Group Stage | UEFA Champions League 21/22 |
| 1 | Munir El Haddadi | Group Stage | UEFA Champions League 20/21 |
| 1 | Jules Kounde | Group Stage | UEFA Champions League 20/21 |
| 1 | Suso | Round of 16 | UEFA Champions League 20/21 |
| 1 | Simon Kjaer | Group Stage | UEFA Champions League 17/18 |
| 1 | Ganso | Group Stage | UEFA Champions League 17/18 |
| 1 | Ever Banega | Group Stage | UEFA Champions League 17/18 |
| 1 | Pablo Sarabia | Quarter-finals | UEFA Champions League 17/18 |
| 1 | Clement Lenglet | Group Stage | UEFA Champions League 17/18 |
| 1 | Joaquin Correa | Group Stage | UEFA Champions League 17/18 |
| 1 | Guido Pizarro | Group Stage | UEFA Champions League 17/18 |
| 1 | Steven N'Zonzi | Group Stage | UEFA Champions League 16/17 |
| 1 | Pablo Sarabia | Round of 16 | UEFA Champions League 16/17 |
| 1 | Sergio Escudero | Group Stage | UEFA Champions League 16/17 |
| 1 | Joaquin Correa | Round of 16 | UEFA Champions League 16/17 |
| 1 | Luciano Vietto | Group Stage | UEFA Champions League 16/17 |
| 1 | Samir Nasri | Group Stage | UEFA Champions League 16/17 |
| 1 | Nicolas Pareja | Group Stage | UEFA Champions League 16/17 |
| 1 | Kevin Gameiro | Group Stage | UEFA Champions League 15/16 |
| 1 | Vitolo | Group Stage | UEFA Champions League 15/16 |
| 1 | Fernando Llorente | Group Stage | UEFA Champions League 15/16 |
| 1 | Benoit Tremoulinas | Group Stage | UEFA Champions League 15/16 |
| 1 | Lucas Ocampos | Group Section | UEFA Champions League 23/24 |
| 1 | Renato | Group Stage | UEFA Champions League 09/10 |
| 1 | Adriano | Group Stage | UEFA Champions League 09/10 |
| 1 | Alvaro Negredo | Round of 16 | UEFA Champions League 09/10 |
| 1 | Abdoulay Konko | Group Stage | UEFA Champions League 09/10 |
| 1 | Diego Perotti | Round of 16 | UEFA Champions League 09/10 |
| 1 | Arouna Kone | Group Stage | UEFA Champions League 07/08 |
