| 6 | Dani Alves | Group Stage | UEFA Champions League 14/15 |
| 6 | Luis Enrique | First Group Stage | UEFA Champions League 01/02 |
| 5 | Neymar | Group Stage | UEFA Champions League 16/17 |
| 5 | Gabri | First Group Stage | UEFA Champions League 02/03 |
| 5 | Luis Figo | Quarter-finals | UEFA Champions League 99/00 |
| 5 | Carles Puyol | First Group Stage | UEFA Champions League 01/02 |
| 4 | Ivan Rakitic | Group Stage | UEFA Champions League 16/17 |
| 4 | Francesc Fabregas | Group Stage | UEFA Champions League 13/14 |
| 4 | Gerard Pique | Group Stage | UEFA Champions League 09/10 |
| 4 | Oleguer | Group Stage | UEFA Champions League 05/06 |
| 4 | Carles Puyol | Group Stage | UEFA Champions League 05/06 |
| 4 | Phillip Cocu | First Group Stage | UEFA Champions League 01/02 |
| 3 | Sergio Busquets | Group Stage | UEFA Champions League 22/23 |
| 3 | Gerard Pique | Group Stage | UEFA Champions League 19/20 |
| 3 | Arturo Vidal | Group Stage | UEFA Champions League 19/20 |
| 3 | Sergio Busquets | Group Stage | UEFA Champions League 18/19 |
| 3 | Nelson Semedo | Group Stage | UEFA Champions League 18/19 |
| 3 | Luis Suarez | Group Stage | UEFA Champions League 18/19 |
| 3 | Nelson Semedo | Group Stage | UEFA Champions League 17/18 |
| 3 | Gerard Pique | Group Stage | UEFA Champions League 17/18 |
| 3 | Sergio Busquets | Group Stage | UEFA Champions League 16/17 |
| 3 | Gerard Pique | Group Stage | UEFA Champions League 15/16 |
| 3 | Dani Alves | Group Stage | UEFA Champions League 15/16 |
| 3 | Andreas Christensen | Round of 16 | UEFA Champions League 23/24 |
| 3 | Sergio Roberto | Group Section | UEFA Champions League 23/24 |
| 3 | Alexis Sanchez | Group Stage | UEFA Champions League 13/14 |
| 3 | Pedro Rodriguez | Group Stage | UEFA Champions League 12/13 |
| 3 | Javier Mascherano | Group Stage | UEFA Champions League 12/13 |
| 3 | Adriano | Group Stage | UEFA Champions League 12/13 |
| 3 | Gerard Pique | Round of 16 | UEFA Champions League 12/13 |
| 3 | Jordi Alba | Group Stage | UEFA Champions League 12/13 |
| 3 | Dani Alves | Group Stage | UEFA Champions League 11/12 |
| 3 | Gerard Pique | Group Stage | UEFA Champions League 10/11 |
| 3 | Andres Iniesta | Group Stage | UEFA Champions League 10/11 |
| 3 | Carles Puyol | Group Stage | UEFA Champions League 09/10 |
| 3 | Dani Alves | Round of 16 | UEFA Champions League 08/09 |
| 3 | Rafael Marquez (Mex) | Group Stage | UEFA Champions League 08/09 |
| 3 | Carles Puyol | Round of 16 | UEFA Champions League 08/09 |
| 3 | Miguel Angel Nadal | Quarter-finals | UEFA Champions League 94/95 |
| 3 | Rafael Marquez (Mex) | Group Stage | UEFA Champions League 07/08 |
| 3 | Yaya Toure | Group Stage | UEFA Champions League 07/08 |
| 3 | Carles Puyol | Group Stage | UEFA Champions League 07/08 |
| 3 | Deco | Group Stage | UEFA Champions League 05/06 |
| 3 | Thiago Motta | First Group Stage | UEFA Champions League 02/03 |
| 3 | Fernando Navarro | First Group Stage | UEFA Champions League 02/03 |
| 3 | Abelardo | Second Group Stage | UEFA Champions League 99/00 |
| 3 | Gabri | Semi-finals | UEFA Champions League 99/00 |
| 3 | Luis Enrique | First Group Stage | UEFA Champions League 00/01 |
| 2 | Gavi | Group Stage | UEFA Champions League 22/23 |
| 2 | Eric Garcia | Group Stage | UEFA Champions League 21/22 |
| 2 | Gavi | Group Stage | UEFA Champions League 21/22 |
| 2 | Gerard Pique | Group Stage | UEFA Champions League 21/22 |
| 2 | Clement Lenglet | Group Stage | UEFA Champions League 20/21 |
| 2 | Jordi Alba | Group Stage | UEFA Champions League 19/20 |
| 2 | Antoine Griezmann | Group Stage | UEFA Champions League 19/20 |
| 2 | Lionel Messi | Group Stage | UEFA Champions League 19/20 |
| 2 | Luis Suarez | Round of 16 | UEFA Champions League 19/20 |
| 2 | Nelson Semedo | Group Stage | UEFA Champions League 19/20 |
| 2 | Sergio Busquets | Group Stage | UEFA Champions League 19/20 |
| 2 | Jordi Alba | Group Stage | UEFA Champions League 18/19 |
