| 4 | Joan Jordan | Group Stage | UEFA Champions League 20/21 |
| 4 | Ever Banega | Group Stage | UEFA Champions League 17/18 |
| 4 | Seydou Keita | Group Stage | UEFA Champions League 07/08 |
| 3 | Oscar Rodriguez | Group Stage | UEFA Champions League 20/21 |
| 3 | Marcos Acuna | Group Stage | UEFA Champions League 20/21 |
| 3 | Gabriel Mercado | Group Stage | UEFA Champions League 17/18 |
| 3 | Gabriel Mercado | Group Stage | UEFA Champions League 16/17 |
| 3 | Lucas Ocampos | Group Section | UEFA Champions League 23/24 |
| 3 | Adriano | Group Stage | UEFA Champions League 07/08 |
| 2 | Nemanja Gudelj | Group Stage | UEFA Champions League 22/23 |
| 2 | Gonzalo Montiel | Group Stage | UEFA Champions League 22/23 |
| 2 | Jose Angel Carmona | Group Stage | UEFA Champions League 22/23 |
| 2 | Erik Lamela | Group Stage | UEFA Champions League 22/23 |
| 2 | Thomas Delaney | Group Stage | UEFA Champions League 21/22 |
| 2 | Diego Carlos | Group Stage | UEFA Champions League 21/22 |
| 2 | Youssef En-Nesyri | Group Stage | UEFA Champions League 21/22 |
| 2 | Lucas Ocampos | Group Stage | UEFA Champions League 21/22 |
| 2 | Jules Kounde | Group Stage | UEFA Champions League 20/21 |
| 2 | Sergio Escudero | Group Stage | UEFA Champions League 17/18 |
| 2 | Guido Pizarro | Group Stage | UEFA Champions League 17/18 |
| 2 | Joaquin Correa | Round of 16 | UEFA Champions League 17/18 |
| 2 | Wissam Ben Yedder | Group Stage | UEFA Champions League 17/18 |
| 2 | Steven N'Zonzi | Round of 16 | UEFA Champions League 17/18 |
| 2 | Nicolas Pareja | Group Stage | UEFA Champions League 16/17 |
| 2 | Samir Nasri | Group Stage | UEFA Champions League 16/17 |
| 2 | Vicente Iborra | Group Stage | UEFA Champions League 16/17 |
| 2 | Vitolo | Group Stage | UEFA Champions League 16/17 |
| 2 | Sergio Ramos | Group Section | UEFA Champions League 23/24 |
| 2 | Boubakary Soumare | Group Section | UEFA Champions League 23/24 |
| 2 | Fernando Navarro | Group Stage | UEFA Champions League 09/10 |
| 2 | Andres Palop | Group Stage | UEFA Champions League 07/08 |
| 2 | Dani Alves | Group Stage | UEFA Champions League 07/08 |
| 1 | Rafa Mir | Group Stage | UEFA Champions League 22/23 |
| 1 | Joan Jordan | Group Stage | UEFA Champions League 22/23 |
| 1 | Kike Salas | Group Stage | UEFA Champions League 22/23 |
| 1 | Yassine Bounou | Group Stage | UEFA Champions League 22/23 |
| 1 | Suso | Group Stage | UEFA Champions League 21/22 |
| 1 | Gonzalo Montiel | Group Stage | UEFA Champions League 21/22 |
| 1 | Rafa Mir | Group Stage | UEFA Champions League 21/22 |
| 1 | Fernando | Group Stage | UEFA Champions League 21/22 |
| 1 | Ivan Rakitic | Group Stage | UEFA Champions League 21/22 |
| 1 | Erik Lamela | Group Stage | UEFA Champions League 21/22 |
| 1 | Joan Jordan | Group Stage | UEFA Champions League 21/22 |
| 1 | Jesus Navas | Group Stage | UEFA Champions League 21/22 |
| 1 | Karim Rekik | Group Stage | UEFA Champions League 21/22 |
| 1 | Ludwig Augustinsson | Group Stage | UEFA Champions League 21/22 |
| 1 | Oliver Torres | Group Stage | UEFA Champions League 20/21 |
| 1 | Nemanja Gudelj | Group Stage | UEFA Champions League 20/21 |
| 1 | Fernando | Round of 16 | UEFA Champions League 20/21 |
| 1 | Oussama Idrissi | Group Stage | UEFA Champions League 20/21 |
| 1 | Diego Carlos | Round of 16 | UEFA Champions League 20/21 |
| 1 | Karim Rekik | Group Stage | UEFA Champions League 20/21 |
| 1 | Sergi Gomez | Group Stage | UEFA Champions League 20/21 |
| 1 | Youssef En-Nesyri | Group Stage | UEFA Champions League 20/21 |
| 1 | Pablo Sarabia | Round of 16 | UEFA Champions League 17/18 |
| 1 | Nicolas Pareja | Group Stage | UEFA Champions League 17/18 |
| 1 | Steven N'Zonzi | Group Stage | UEFA Champions League 16/17 |
| 1 | Franco Vazquez | Group Stage | UEFA Champions League 16/17 |
| 1 | Sergio Escudero | Round of 16 | UEFA Champions League 16/17 |
| 1 | Adil Rami | Group Stage | UEFA Champions League 16/17 |
