| Group E | P | W | D | L | GF | GA | GD | points |
|---|---|---|---|---|---|---|---|---|
 Real Madrid | 6 | 4 | 1 | 1 | 15 | 7 | 8 | 13 |
 FC Porto | 6 | 4 | 0 | 2 | 9 | 6 | 3 | 12 |
 Olympiakos | 6 | 2 | 1 | 3 | 9 | 12 | -3 | 7 |
Molde FK | 6 | 1 | 0 | 5 | 6 | 14 | -8 | 3 |
Tuesday 2 November 1999 | |||||||
| Molde FK | 0 | - | 1 | Real Madrid | 18:45 | STATS» | |
| Olympiakos | 1 | - | 0 | FC Porto | 18:45 | STATS» | |
Tuesday 26 October 1999 | |||||||
| FC Porto | 3 | - | 1 | Molde FK | 18:45 | STATS» | |
| Real Madrid | 3 | - | 0 | Olympiakos | 18:45 | STATS» | |
Wednesday 20 October 1999 | |||||||
| Molde FK | 3 | - | 2 | Olympiakos | 18:45 | STATS» | |
| FC Porto | 2 | - | 1 | Real Madrid | 18:45 | STATS» | |
Tuesday 28 September 1999 | |||||||
| Olympiakos | 3 | - | 1 | Molde FK | 18:45 | STATS» | |
| Real Madrid | 3 | - | 1 | FC Porto | 18:45 | STATS» | |
Tuesday 21 September 1999 | |||||||
| Real Madrid | 4 | - | 1 | Molde FK | 18:45 | STATS» | |
| FC Porto | 2 | - | 0 | Olympiakos | 18:45 | STATS» | |
Wednesday 15 September 1999 | |||||||
| Molde FK | 0 | - | 1 | FC Porto | 18:45 | STATS» | |
| Olympiakos | 3 | - | 3 | Real Madrid | 18:45 | STATS» | |