| Red | Players | Sections | Competition |
|---|---|---|---|
| 1 | Eric Garcia | Group Stage | UEFA Champions League 21/22 |
| 1 | Gerard Pique | Group Stage | UEFA Champions League 20/21 |
| 1 | Arturo Vidal | Round of 16 | UEFA Champions League 19/20 |
| 1 | Samuel Umtiti | Group Stage | UEFA Champions League 18/19 |
| 1 | Gerard Pique | Group Stage | UEFA Champions League 17/18 |
| 1 | Jeremy Mathieu | Group Stage | UEFA Champions League 16/17 |
| 1 | Gavi | Group Section | UEFA Champions League 23/24 |
| 1 | Ronald Araujo | Quarter-finals | UEFA Champions League 23/24 |
| 1 | Rafinha | Group Stage | UEFA Champions League 14/15 |
| 1 | Sergio Busquets | Group Stage | UEFA Champions League 12/13 |
| 1 | Jose Manuel Pinto | Semi-finals | UEFA Champions League 10/11 |
| 1 | Carles Puyol | Quarter-finals | UEFA Champions League 09/10 |
| 1 | Eric Abidal | Semi-finals | UEFA Champions League 08/09 |
| 1 | Pep Guardiola | Group Stage | UEFA Champions League 98/99 |
| 1 | Ruud Hesp | Group Stage | UEFA Champions League 97/98 |
| 1 | Sergi | Group Stage | UEFA Champions League 97/98 |
UEFA Champions League 23/24 Top goal scorers