| Red | Players | Sections | Competition |
|---|---|---|---|
| 1 | Dmitri Chistyakov | Group Stage | UEFA Champions League 21/22 |
| 1 | Douglas Santos | Group Stage | UEFA Champions League 19/20 |
| 1 | Alexandr Anyukov | Group Stage | UEFA Champions League 15/16 |
| 1 | Domenico Criscito | Round of 16 | UEFA Champions League 15/16 |
| 1 | Axel Witsel | Group Stage | UEFA Champions League 13/14 |
| 1 | Vladimir Bystrov | Group Stage | UEFA Champions League 12/13 |
| 1 | Bruno Alves | Group Stage | UEFA Champions League 11/12 |
| 1 | Sebastien Puygrenier | Group Stage | UEFA Champions League 08/09 |
UEFA Champions League 23/24 Top goal scorers