| MD | Players | Clubs | Nationality | DOB | A(D) |
|---|---|---|---|---|---|
| 21-Aug-2013 |  Oliver Torres | Atletico Madrid | Spain | 10-Nov-1994 | 18(285) |
| 21-Aug-2013 | Leo Baptistao | Atletico Madrid | Brazil | 26-Aug-1992 | 20(360) |
| 21-Aug-2013 | Thibaut Courtois | Atletico Madrid | Belgium | 11-May-1992 | 21(102) |
| 21-Aug-2013 |  Neymar | Barcelona | Brazil | 05-Feb-1992 | 21(198) |
| 21-Aug-2013 | Jorge Koke | Atletico Madrid | Spain | 08-Jan-1992 | 21(226) |
| 21-Aug-2013 | Jordi Alba | Barcelona | Spain | 21-Mar-1989 | 24(153) |
| 21-Aug-2013 | Alexis Sanchez | Barcelona | Chile | 19-Dec-1988 | 24(245) |
| 21-Aug-2013 | Diego Costa | Atletico Madrid | Spain | 07-Oct-1988 | 24(318) |
| 21-Aug-2013 | Sergio Busquets | Barcelona | Spain | 16-Jul-1988 | 25(36) |
| 28-Aug-2013 | Adrian Lopez | Atletico Madrid | Spain | 08-Jan-1988 | 25(233) |
| 21-Aug-2013 | Alex Song | Barcelona | Cameroon | 09-Sep-1987 | 25(347) |
| 21-Aug-2013 | Pedro Rodriguez | Barcelona | Spain | 28-Jul-1987 | 26(25) |
| 21-Aug-2013 | Lionel Messi | Barcelona | Argentina | 24-Jun-1987 | 26(59) |
| 28-Aug-2013 | Francesc Fabregas | Barcelona | Spain | 04-May-1987 | 26(117) |
| 21-Aug-2013 | Mario Suarez | Atletico Madrid | Spain | 24-Feb-1987 | 26(179) |
| 21-Aug-2013 | Gerard Pique | Barcelona | Spain | 02-Feb-1987 | 26(201) |
| 21-Aug-2013 | Arda Turan | Atletico Madrid | Turkey | 30-Jan-1987 | 26(204) |
| 21-Aug-2013 | Diego Godin | Atletico Madrid | Uruguay | 16-Jan-1986 | 27(217) |
| 21-Aug-2013 | Cristian Rodriguez | Atletico Madrid | Uruguay | 30-Sep-1985 | 27(325) |
| 21-Aug-2013 | Filipe Luis | Atletico Madrid | Brazil | 09-Aug-1985 | 28(12) |
| 21-Aug-2013 | Juanfran | Atletico Madrid | Spain | 09-Jan-1985 | 28(224) |
| 21-Aug-2013 | Joao Miranda | Atletico Madrid | Brazil | 07-Sep-1984 | 28(348) |
| 21-Aug-2013 | Javier Mascherano | Barcelona | Argentina | 08-Jun-1984 | 29(74) |
| 21-Aug-2013 | Andres Iniesta | Barcelona | Spain | 11-May-1984 | 29(102) |
| 21-Aug-2013 | Fernandez Gabi | Atletico Madrid | Spain | 10-Jul-1983 | 30(43) |
| 21-Aug-2013 | Dani Alves | Barcelona | Brazil | 06-May-1983 | 30(108) |
| 21-Aug-2013 | Victor Valdes | Barcelona | Spain | 14-Jan-1982 | 31(220) |
| 21-Aug-2013 | David Villa | Atletico Madrid | Spain | 03-Feb-1981 | 32(199) |
| 21-Aug-2013 | Xavi | Barcelona | Spain | 25-Jan-1980 | 33(209) |
MD = Match date,
DOB = Date Of Birth,
A(D) = Age(Days).