| Date | Result | OPP | FS | Home/Away |
|---|---|---|---|---|
| 26-Aug-2012 | draw |  Deportivo La Coruna | 3-3 | home |
| 15-Sep-2012 | win |  Celta Vigo | 2-1 | home |
| 29-Sep-2012 | win |  Real Zaragoza | 2-0 | home |
| 03-Nov-2012 | win |  Atletico Madrid | 2-0 | home |
| 11-Nov-2012 | draw |  Real Valladolid | 1-1 | away |
| 17-Nov-2012 | win |  Espanyol | 2-1 | home |
| 01-Dec-2012 | lose |  Real Sociedad | 2-5 | home |
| 08-Dec-2012 | win |  Osasuna | 0-1 | away |
| 21-Dec-2012 | win |  Getafe | 4-2 | home |
| 12-Jan-2013 | win |  Sevilla | 2-0 | home |
| 26-Jan-2013 | win | Deportivo La Coruna | 2-3 | away |
| 03-Feb-2013 | draw |  Barcelona | 1-1 | home |
| 09-Feb-2013 | win | Celta Vigo | 0-1 | away |
| 17-Feb-2013 | win |  RCD Mallorca | 2-0 | home |
| 16-Mar-2013 | win |  Real Betis | 3-0 | home |
| 31-Mar-2013 | draw | Atletico Madrid | 1-1 | away |
| 07-Apr-2013 | win | Real Valladolid | 2-1 | home |
| 20-Apr-2013 | win |  Malaga | 5-1 | home |
| 28-Apr-2013 | lose | Real Sociedad | 4-2 | away |
| 04-May-2013 | win | Osasuna | 4-0 | home |
| 12-May-2013 | win |  Rayo Vallecano | 0-4 | away |
| 18-May-2013 | win | Getafe | 0-1 | away |
| 26-May-2013 | win |  Granada CF | 1-0 | home |
| 01-Jun-2013 | lose | Sevilla | 4-3 | away |
Overall ( 17 wins,4 draw,3 lost )
Home ( 12 wins,2 draw,1 lost )
Away ( 5 wins,2 draw,2 lost )
OPP = Opposition,
FS = Final score.