| Date | Result | OPP | FS | Home/Away |
|---|---|---|---|---|
| 19-Aug-2012 | win |  Athletic Bilbao | 3-5 | away |
| 26-Sep-2012 | lose |  Atletico Madrid | 2-4 | home |
| 17-Sep-2012 | win |  Real Valladolid | 0-1 | away |
| 22-Sep-2012 | win |  Espanyol | 1-0 | home |
| 06-Oct-2012 | win |  Real Sociedad | 2-0 | home |
| 27-Oct-2012 | win |  Valencia | 1-0 | home |
| 05-Nov-2012 | win |  Getafe | 2-4 | away |
| 24-Nov-2012 | win |  Real Madrid | 1-0 | home |
| 02-Dec-2012 | win |  Deportivo La Coruna | 2-3 | away |
| 17-Dec-2012 | win |  Celta Vigo | 0-1 | away |
| 22-Dec-2012 | lose |  RCD Mallorca | 1-2 | home |
| 04-Jan-2013 | win |  Real Zaragoza | 1-2 | away |
| 13-Jan-2013 | win |  Levante | 2-0 | home |
| 21-Jan-2013 | draw | Athletic Bilbao | 1-1 | home |
| 24-Feb-2013 | win |  Malaga | 3-0 | home |
| 03-Mar-2013 | draw | Real Sociedad | 3-3 | away |
| 08-Mar-2013 | win |  Osasuna | 2-1 | home |
| 05-Apr-2013 | win |  Granada CF | 1-5 | away |
| 05-May-2013 | lose |  Barcelona | 4-2 | away |
| 12-May-2013 | win | Celta Vigo | 1-0 | home |
| 26-May-2013 | win | Real Zaragoza | 4-0 | home |
Overall ( 16 wins,2 draw,3 lost )
Home ( 9 wins,1 draw,2 lost )
Away ( 7 wins,1 draw,1 lost )
OPP = Opposition,
FS = Final score.