| MD | Players | Clubs | Nationality | DOB | A(D) |
|---|---|---|---|---|---|
| 11-Mar-2012 |  Paul Quaye | Espanyol | Ghana | 16-Sep-1995 | 16(177) |
| 28-Aug-2011 |  Joel Valencia | Real Zaragoza | Ecuador | 16-Nov-1994 | 16(285) |
| 27-Aug-2011 |  Alvaro Vadillo | Real Betis | Spain | 12-Sep-1994 | 16(349) |
| 03-Dec-2011 |  Moises Gomez | Villarreal | Spain | 20-Oct-1994 | 17(44) |
| 29-Oct-2011 |  Gerard Deulofeu | Barcelona | Spain | 13-Mar-1994 | 17(230) |
| 27-Aug-2011 |  Jairo Samperio | Racing Santander | Spain | 11-Jul-1993 | 18(47) |
| 28-Aug-2011 |  Jose Campana | Sevilla | Spain | 31-May-1993 | 18(89) |
| 14-Jan-2012 |  Paco Alcacer | Valencia | Spain | 30-Aug-1993 | 18(137) |
| 21-Sep-2011 |  Raphael Varane | Real Madrid | France | 25-Apr-1993 | 18(149) |
| 20-Nov-2011 |  Jonas Ramalho | Athletic Bilbao | Spain | 10-Jun-1993 | 18(163) |
| 27-Aug-2011 | Juan Bernat | Valencia | Spain | 01-Mar-1993 | 18(179) |
| 26-Oct-2011 | Jorgi Orti | Real Zaragoza | Spain | 28-Apr-1993 | 18(181) |
| 11-Dec-2011 |  Juanmi | Malaga | Spain | 20-May-1993 | 18(205) |
| 05-May-2012 |  Pablo Mari | RCD Mallorca | Spain | 31-Aug-1993 | 18(248) |
| 28-Aug-2011 | Iker Muniain | Athletic Bilbao | Spain | 19-Dec-1992 | 18(252) |
| 09-Apr-2012 | Dani Sotres | Racing Santander | Spain | 21-May-1993 | 18(324) |
| 11-Feb-2012 | Khouma Babacar | Racing Santander | Senegal | 17-Mar-1993 | 18(331) |
| 29-Oct-2011 |  Ruben Pardo | Real Sociedad | Spain | 22-Oct-1992 | 19(6) |
| 22-Sep-2011 | Sergio | Real Betis | Spain | 07-Sep-1992 | 19(14) |
| 24-Mar-2012 | Jese | Real Madrid | Spain | 26-Feb-1993 | 19(26) |
| 25-Oct-2011 | Luis Alberto | Sevilla | Spain | 28-Sep-1992 | 19(26) |
| 12-May-2012 | Nono | Real Betis | Spain | 30-Mar-1993 | 19(43) |
| 28-Aug-2011 | Thievy Bifouma | Espanyol | Republic of the Congo | 13-May-1992 | 19(106) |
| 28-Aug-2011 |  Pablo Sarabia | Getafe | Spain | 11-May-1992 | 19(108) |
| 28-Aug-2011 |  Thibaut Courtois | Atletico Madrid | Belgium | 11-May-1992 | 19(108) |
| 04-Mar-2012 | Alvaro Morata | Real Madrid | Spain | 23-Oct-1992 | 19(132) |
| 12-Sep-2011 | Isco | Malaga | Spain | 21-Apr-1992 | 19(143) |
| 28-Aug-2011 |  Lass Bangoura | Rayo Vallecano | Guinea | 30-Mar-1992 | 19(150) |
| 28-Aug-2011 | Jordi Amat | Espanyol | Spain | 21-Mar-1992 | 19(159) |
MD = Match date,
DOB = Date Of Birth,
A(D) = Age(Days).