| Date | Result | OPP | FS | Home/Away |
|---|---|---|---|---|
| 19-Aug-2012 | draw |  Valencia | 1-1 | home |
| 26-Aug-2012 | lose |  Getafe | 2-1 | away |
| 02-Sep-2012 | win |  Granada CF | 3-0 | home |
| 24-Sep-2012 | win |  Rayo Vallecano | 0-2 | away |
| 07-Oct-2012 | draw |  Barcelona | 2-2 | away |
| 20-Oct-2012 | win |  Celta Vigo | 2-0 | home |
| 28-Oct-2012 | win |  RCD Mallorca | 0-5 | away |
| 03-Nov-2012 | win |  Real Zaragoza | 4-0 | home |
| 11-Nov-2012 | win |  Levante | 1-2 | away |
| 17-Nov-2012 | win |  Athletic Bilbao | 5-1 | home |
| 01-Dec-2012 | win |  Atletico Madrid | 2-0 | home |
| 06-Jan-2013 | win |  Real Sociedad | 4-3 | home |
| 20-Jan-2013 | win | Valencia | 0-5 | away |
| 27-Jan-2013 | win | Getafe | 4-0 | home |
| 09-Feb-2013 | win |  Sevilla | 4-1 | home |
| 17-Feb-2013 | win | Rayo Vallecano | 2-0 | home |
| 02-Mar-2013 | win | Barcelona | 2-1 | home |
| 10-Mar-2013 | win | Celta Vigo | 1-2 | away |
| 14-Apr-2013 | win | Athletic Bilbao | 0-3 | away |
| 20-Apr-2013 | win |  Real Betis | 3-1 | home |
| 08-May-2013 | win |  Malaga | 6-2 | home |
| 26-May-2013 | draw | Real Sociedad | 3-3 | away |
| 01-Jun-2013 | win |  Osasuna | 4-2 | home |
Overall ( 19 wins,3 draw,1 lost )
Home ( 13 wins,1 draw,0 lost )
Away ( 6 wins,2 draw,1 lost )
OPP = Opposition,
FS = Final score.