| Group A | P | W | D | L | GF | GA | GD | points |
|---|---|---|---|---|---|---|---|---|
 Napoli | 6 | 5 | 0 | 1 | 20 | 6 | 14 | 15 |
 Liverpool | 6 | 5 | 0 | 1 | 17 | 6 | 11 | 15 |
 AFC Ajax | 6 | 2 | 0 | 4 | 11 | 16 | -5 | 6 |
 Rangers | 6 | 0 | 0 | 6 | 2 | 22 | -20 | 0 |
Tuesday 1 November 2022 | |||||||
| Rangers | 1 | - | 3 | AFC Ajax | 19:00 | STATS» | |
| Liverpool | 2 | - | 0 | Napoli | 19:00 | STATS» | |
Wednesday 26 October 2022 | |||||||
| Napoli | 3 | - | 0 | Rangers | 19:00 | STATS» | |
| AFC Ajax | 0 | - | 3 | Liverpool | 19:00 | STATS» | |
Wednesday 12 October 2022 | |||||||
| Rangers | 1 | - | 7 | Liverpool | 19:00 | STATS» | |
| Napoli | 4 | - | 2 | AFC Ajax | 16:45 | STATS» | |
Tuesday 4 October 2022 | |||||||
| Liverpool | 2 | - | 0 | Rangers | 19:00 | STATS» | |
| AFC Ajax | 1 | - | 6 | Napoli | 19:00 | STATS» | |
Wednesday 14 September 2022 | |||||||
| Rangers | 0 | - | 3 | Napoli | 19:00 | STATS» | |
Tuesday 13 September 2022 | |||||||
| Liverpool | 2 | - | 1 | AFC Ajax | 19:00 | STATS» | |
Wednesday 7 September 2022 | |||||||
| Napoli | 4 | - | 1 | Liverpool | 19:00 | STATS» | |
| AFC Ajax | 4 | - | 0 | Rangers | 16:45 | STATS» | |